gas hydrates

     

Clathrate hyrates (or gas clathrates, gas hydrates, clathrates, hydrates etc) were first documented in 1810 by Sir Humphrey Davy; they are crystalline water based solids physically resembling ice, in which small non polar molecules (typically gases) are trapped inside "cages" of hydrogen bonded water molecules. Without the support of the trapped molecules, the lattice structure of hydrate clathrates would collapse into conventional ice crystal structure or liquid water. Most low molecular weight gases (including O2, H2, N2, CO2, CH4, H2S, Ar, Kr, and Xe), as well as some higher hydrocarbons and freons will form hydrates at suitable temperatures and pressures. Clathrate hydrates are not chemical compounds as the sequestered molecules are never bonded to the lattice. The formation and decomposition of clathrate hydrates are first order phase transitions, not chemical reactions.

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