valence shell electron pair repulsion

     

Valence shell electron pair repulsion (VSEPR) theory (1957) is a moel in chemistry, which is used for predicting the shapes of individual molecules, based upon their extent of electron-pair electrostatic repulsion, determined using steric numbers. The theory is also called the Gillespie-Nyholm theory after the two main developers, and VSEPR is sometimes pronounced as "vesper" which is easier to say. The premise of VSEPR is that a constructed Lewis structure is expanded to show all lone pairs of electrons alongside protruding and projecting bonds, for predicting the geometric shape and lone-pair behavior of a molecule through consideration of the total coordination number.

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